Madalena
A beautiful maiden kidnapped by an evil king and forced to marry him, who rejected being saved in favor of becoming Queen.
Where is she from?
Other than the fact that the entire series is an awesome Alan Menken musical, the really clever twist of the series Galavant is the character Madalena, the beautiful maiden the hero loved and quested to save, only for him to discover that their relationship was entirely physical, that she in fact only really wants power, and is totally down to marry her kidnapper if it means she gets to rule her own kingdom. She's played by Mallory Jansen, is a fantastic series antagonist, and we deserve more of her.